Product ID:GLAZD PENTA
MSDS Date:02/01/1987
FSC:6810
NIIN:00N059768
MSDS Number: CDPPT

VULCAN CHEMICALS

BIRMINGHAM, AL 35253-0689
US

Emergency Phone: 415-821-5338

Info Phone: 316-524-5751

Cage: EO675

VULCAN MATERIALS CO

530390 BIRMINGHAM, AL 35253 US

Telephone: 316-524-5751

Cage: 1B637

PHENOL, PENTACHLORO-; (PENTACHLOROPHENOL) (SARA 313)

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 90%

OSHA PEL 0.5 MG/M3, S

ACGIH TLV: 0.5 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, 2,3,4,6-TETRACHLORO-; (2,3,4,6-TETRACHLOROPHENOL)

CAS: 58-90-2

RTECS: SM9275000

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HYDROXYPOLYCHLORODIBENZO ETHERS

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

DIBENZO-P-DIOXIN, HEXACHLORO-; (HEXACHLORODIBENZO-P-DIOXIN)

CAS: 39227-28-6

RTECS: HP3200000

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

DIBENZO-P-DIOXIN, 1,2,3,4,6,7,8-HEPTACHLORO-;

CAS: 35822-46-9

RTECS: HP3190000

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

HEXACHLORODIBENZOFURAN

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

HEPTACHLORODIBENZOFURAN

Fraction By Weight: TRACE

OSHA PEL N/K

ACGIH TLV: N/K

INDICATE TOX TO HUMANS. OVEREXP SHOULD BE AVOIDED,

RTECS: 9999999ZZ

DEATH. CHRONIC OVEREXP TO TECHNICAL GRADE

RTECS: 9999999ZZ

ANIMALS. U.S. EPA HAS DETERMINED THAT ING 1 CAN PRDCE

RTECS: 9999999ZZ

DURING PREGNANCY SHOULD BE AVOIDED. REPRO TOX TESTS

RTECS: 9999999ZZ

TECHNICAL GRADE & PURIFIED PENTACHLOROPHENOL MAY

RTECS: 9999999ZZ

& PURIFIED PENTACHLOROPHENOL HAVE BEEN FOUND TO BE

RTECS: 9999999ZZ

IN HUMANS, ABSORPTION OF ING

RTECS: 9999999ZZ

CHLORACNE. THIS USUALLY APPEARS AS BLACKHEADS,

RTECS: 9999999ZZ

SEV CASES, INVOLVEMENT MAY BE EXTENSIVE. MILD CASES

RTECS: 9999999ZZ

SKIN CHANGES COMMONLY SEEN W/AGING. CONTACT NEHC FOR

RTECS: 9999999ZZ

TOUCHING BACK OF THROAT W/FINGER. DO NOT

RTECS: 9999999ZZ

THIS PROD IS A METABOLIC STIMULANT.

RTECS: 9999999ZZ

REPRESENTATIVE AT NEAREST EPA REGIONAL

RTECS: 9999999ZZ

INTO APPLICATION EQUIP. TRIPLE RINSE/CLEAN EMPTY

RTECS: 9999999ZZ

(B)(3) PRIOR TO OFFERING FOR RECONDITIONING,

RTECS: 9999999ZZ

REGIONAL OFFICE/STATE AGENCY AUTHORIZED TO ADMIN

RTECS: 9999999ZZ

EMERGENCY & SPILLS. FOLLOW APPLICABLE RESPIRATOR

RTECS: 9999999ZZ

FLAKE/SOLID PENTA. CONTACT NEHC FOR MORE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:CONCS OF 0.3 MG/M3 CAN
CAUSE NOSE IRRIT. CONCS > 1 MG/M3 CAN CAUSE IRRIT OF UPPER RESP
TRACT W/SNEEZING & COUGHING. PERS ACCLIMATED TO ING 1 CAN TOLERATE
LEVELS > 2 MG/M3. SYMPS OF OVEREXP INCL RAPID HEARTBEAT & RESP,
ELEVATED TEMP & BLOOD PRESS, MUSC WEAK, EXCESS SWEATING, DIZZ &
NAUS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:HIGH CONCS CAN CAUSE UNCON, CONVLS &
DEATH GENERALLY FROM CARD ARREST. SKIN:ING 1 IS READILY ABSORBED
THRU INTACT SKIN. ING 1 IN SOLN CAN BE READILY ABSORBED THRU INTACT
SKIN IN TOX AMTS, CAU SING SYSTEMIC POIS & SYMPS DESCRIBED ININHAL
SECTION. ING 1 ON SKIN CAN CAUSE IRRIT. EYES: ING 1 CAUSES IRRIT
(SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: MOVE TO FRESH AIR. IF BRTHG HAS STOPPED, ADMIN ARTF
RESP. CALL MD. SKIN: REMOVE CONTAM CLTHG & SHOES. WASH SKIN THORO
W/SOAP & WATER FOR AT LEAST 15 MIN. WASH CONTAM CLTHG BEFORE REUSE.
EYES: F LUSH IMMED W/WATER FOR AT LEAST 15 MIN.CONT MD. INGEST:
CALL MD/POIS CTL CTR IMMED. IF POSS, VOMIT SHOULD BE INDUCED UNDER
MED SUPERVISION. DRINK 1-2 GLASSES OF WATER & INDUCE VOMIT BY (ING
18)

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE. USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC GASES ARE FORMED BY THERMAL
DECOMPOSITION.

Spill Release Procedures:VENTILATE SPILL AREA & AVOID BREATHING OF
VAPS. CLEAN UP SPILLED MATL (WEAR PROTECTIVE EQUIP) & PLACE IN
CLOSED CONTR FOR NORMAL USE IF POSS/PROPER DISPOSAL. PENTA IS TOXIC
TO FISH & WILDLIFE; DO NOT ALLOW TO CONTAMINATE GROUND/SURFACE
WATERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:FOLLOW PROT CTLS. STORE IN PROPERLY
LABELED CONTRS IN DRY, WELL VENTD AREA. THORO WASH POTENTIALLY
CONTAM CLTHG BEFORE REUSE.
Other Precautions:DO NOT LAUNDER WORK CLOTHES W/OTHER NON-CONTAM CLTHES
&/HOUSEHOLD LAUNDRY. CONTAM CLTHG, BOOTS/EQUIP SHOULD NOT BE TAKEN
HOME. DO NOT REMOVE/DEFACE LABEL. DO NOT REUSE BAGS, DRUMS/BOXES
FOR ANY PURPOS E. COMPLETELY EMPTY BAG/DRUM (ING 21)

Respiratory Protection:WHERE CONCS OF PENTACHLOROPHENOL EXCEEDS/ARE
LIKELY TO EXCEED 0.5 MG/M3, A NIOSH APPRVD ORG VAP-DUST FILTER TYPE
RESP IS ACCEPTABLE. NIOSH APPRVD SCBA/AIR LINE RESP, W/FULL
FACEPIECE, IS REQUIRED FOR CONCS > 150.0 MG/M3/DURING (ING 24)
Ventilation:DO NOT USE IN CLSD/CONFINED SPACE. OPEN DOORS &/WINDOWS.
USE VENT TO MAINTAIN EXPOS LEVELS BELOW 0.5 MG/M3.
Protective Gloves:PVC, NEOPRENE, NITRILE LATEX/EQUIVALENT.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR TIGHTLY WOVEN CLTHG INCL LONG SLEEVE SHIRT WHEN HNDLG (ING 25)
Work Hygienic Practices:CONT LENSES SHOULD NOT BE WORN. AVOID CONT
W/SKIN & BRTHG DUST. CONTACT NEHC FOR MORE SPECIFIC INFORMATION .
Supplemental Safety and Health
EFTS OF OVEREXP:AT 1 MG/M3. IF EXPOS IS PRLNG, SLIGHT TRANSIENT CORNEAL
DMG CAN OCCUR. INGEST:SINGLE DOSE TOX IS HIGH. SYMPS OF INGEST ARE
THOSE DESCRIBED IN INHAL SECTION. NOTE:ING 1 EXPOS BY ANY RTE MAY
RSLT IN LATE DEVEL OF SKIN CNDTN KNOWN AS CHLORACNE.
CHRONIC:FINDING OF CHRONIC TOX EFTS IN LAB ANIMALS MAY (ING 8)

Boiling Pt:B.P. Text:590F,310C
Melt/Freeze Pt:M.P/F.P Text:-310F,-190C
Solubility in Water:14 PPM @ 20C
Appearance and Odor:LIGHT BROWN OR TAN FLAKE OR SOLID
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND ALKALIES.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS LISTED BELOW.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE,
CHLORINATED HYDROCARBONS.

Waste Disposal Methods:PESTICIDE WASTES ARE ACUTELY HAZ. IMPROPER DISP
OF EXCESS PESTICIDE, SPRAY MIX/RINSATE IS A VIOLATION OF FED LAW.
IF THESE WASTES CANNOT BE DISP OF BY USE ACCORDING TO LABEL
INSTRUCTIONS, CONT YOUR ST ATE PESTICIDE/ENVIRON CTL AGENCY/HAZ
WASTE(ING 20)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.